I'm no expert, but my understanding is that the pressure is the big issue. The Mil brass has a thicker case web and walls which does raise the pressure from an identical load in .223. Externally the dimensions are identical; but the mil brass will take more abuse (at least the first time). The other thing I've heard over the years, although I've never taken the time to confirm it personally, is the chamber for a 5.56 gun will be looser than a .223 owing to the desire of the military for the gun to continue to work when dirty, and that it will have a longer throat. They want the gun to continue to work in battlefield conditions, so the chamber is opened up a bit. The Brits were famous for this on a lot of the Lee-Enfields; I have one of those where the fired brass swells out almost as far as the case rim. Manufacturers of civilian .223's aren't concerned about the same things, so the chambers are SAAMI spec.
I've also found most Mil 5.56 brass to be harder than a lot of Civ brass, with the exception of the Federal-produced LC brass used for the newer frangible training ammo. That is fairly soft and reforms/reloads rather well.
The one caveat to all this is the Wylde chamber. This is sort of a compromise between the two; as I understand it it's basically a .223 chamber with a longer throat and will shoot either .223 or 5.56 ammo fine.




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