If you are serious about this situation I would highly recommend purchasing Jim Murray's: Whiskey Bible
Very good read and this guy is pretty much spot on on describing each individual whiskeys unique notes.
My personal opinions on the nectar of the God's are as follows:
Johnny Walker- Over priced, especially Blue label.
Jack Daniels-Oily in taste and buying Gent's Jack is like choosing a V6 Camaro over a V8 (bland). Green label tastes the best.
Best surprise whiskey-Hibiki 12-
Best Scotch- MaCallan 12 Sherry Oak or 15 Fine Oak. Both are dangerously drinkable and I have yet to meet a Scotch drinker let alone whiskey drinker that does not enjoy a good sip of this stuff.
Best Bourbon-4 Roses or Maker's 46
Either drop by Barnes & Nobles or get with one of your buddies who knows whiskeys. No one like a faker, let alone a fake whiskey lover. In the end, you pick what YOU think tastes good. Piss on everyone else who thinks otherwise because YOU are the one paying the tab and all they have to do is smile, nod, and enjoy your company. Be mindful that there will always be those who nitpick on shit like "oh I wish they had <insert random $$$ brand here> scoff.
Enjoy your whiskey tasting adventure
Cheers
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