Sounds like he worded the question poorly. If he was saying the /22 was the used and could not be in that sn, then yes the next available would be 145.36.4.1 and .2. I would have given the same answer as you did with the question worded like that.
If I was doing that hire, seeing you give me the info of the sn that was given to you, that would be good enough for me,
You should have asked him if he can do IPv6 calcs.